Chemical Engineering Thermodynamics I
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INTRODUCTION AND FIRST LAW OF THERMODYNAMICS
The scope of thermodynamics, Dimensions and units, Measures of amount or size, Force, temperature, pressure, work, energy, heat, etc. Internal Energy, Enthalpy, The first law of thermodynamics, Thermodynamic state, state functions, Energy balance for closed systems, Equilibrium, The Phase rule, The reversible process, Heat capacity, Application of first law of thermodynamics to steady state flow process.
The scope of thermodynamics, Dimensions and units, Measures of amount or size, Force, temperature, pressure, work, energy, heat, etc. Internal Energy, Enthalpy, The first law of thermodynamics, Thermodynamic state, state functions, Energy balance for closed systems, Equilibrium, The Phase rule, The reversible process, Heat capacity, Application of first law of thermodynamics to steady state flow process.
VOLUMETRIC PROPERTIES OF PURE FLUIDS
PVT behavior of pure substances, Ideal and non-ideal gases, Equation of states, Virial, Cubic, Vanderwaals EOS, Redlich/Kwong (RK) EOS etc., Calculation of constants in terms of Pc, Tc, Vc. Generalized Correlations for gases and liquids.
PVT behavior of pure substances, Ideal and non-ideal gases, Equation of states, Virial, Cubic, Vanderwaals EOS, Redlich/Kwong (RK) EOS etc., Calculation of constants in terms of Pc, Tc, Vc. Generalized Correlations for gases and liquids.
HEAT EFFECTS
Sensible heat effects, Temperature dependence of the heat capacity, Latent heats of pure substances, Approximate methods for the estimation of the latent heat of vaporization, Standard heat of reaction, Standard heat of formation, Standard heat of combustion, Temperature Dependence of ?H°, Heat effects of Industrial Reactions.
Sensible heat effects, Temperature dependence of the heat capacity, Latent heats of pure substances, Approximate methods for the estimation of the latent heat of vaporization, Standard heat of reaction, Standard heat of formation, Standard heat of combustion, Temperature Dependence of ?H°, Heat effects of Industrial Reactions.
SECOND LAW OF THERMODYNAMICS
Statements of second law of thermodynamics, Heat engines, Thermodynamic Temperature Scales, Concept of entropy, Entropy changes of an Ideal Gas, Third law of thermodynamics
Statements of second law of thermodynamics, Heat engines, Thermodynamic Temperature Scales, Concept of entropy, Entropy changes of an Ideal Gas, Third law of thermodynamics
THERMODYNAMIC PROPERTIES OF FLUIDS
The fundamental property relations for homogeneous phases, Maxwell’s equations, Residual properties, Mathematical relations among thermodynamic properties, Two phase systems, Thermodynamic diagrams.
The fundamental property relations for homogeneous phases, Maxwell’s equations, Residual properties, Mathematical relations among thermodynamic properties, Two phase systems, Thermodynamic diagrams.
THERMODYNAMICS OF FLOW PROCESS
Fundamental equations and relationships, flow in pipes, maximum velocity in pipe flow, nozzles, Single and Multistage compressors and ejectors.
Fundamental equations and relationships, flow in pipes, maximum velocity in pipe flow, nozzles, Single and Multistage compressors and ejectors.
REFRIGERATION AND LIQUEFACTION
Carnot refrigerator, Vapor compression cycle, Absorption refrigeration, Choice of refrigerant, Heat pump, Liquefaction processes.
Carnot refrigerator, Vapor compression cycle, Absorption refrigeration, Choice of refrigerant, Heat pump, Liquefaction processes.
